From your chair to your phone case to even your water bottle. Plastics have become an omnipresent material due to their low cost, flexibility, robustness, and versatility. In 2014,more than 300 million tons of plastic were produced, which is the equivalent of 9 Empire State Buildings! Of this, roughly 26% goes towards single-use plastic packaging, and of that amount, only 5% is successfully recycled. Much of it ends up incinerated, landfilled, or leaked into the environment (MacArthur Foundation, 2020).
Because most plastics used today do not naturally biodegrade, waste plastic accumulates over time in soil, rivers, and oceans. In that time, plastics can break down into microplastics, which are potentially consumed by living organisms on land and sea (Lim, 2021). Additionally, most plastics used today are derived from petroleum, which is a non-renewable resource. Thus, our current usage of plastics constitutes a linear "take-make-waste" economy that is not sustainable.
Bioplastics are produced using resources that are natural and renewable. Many bioplastics can also degrade naturally in the environment. Thus, bioplastics can have lower environmental impact than conventional plastics.
Sustainable bioplastics play a critical role in shifting society towards a sustainable "circular" plastics economy. Conventional plastics derived from petroleum cause harm to the planet due to the consumption of non-renewable resources, net positive carbon emissions, and creation of recalcitrant waste.
Sustainable bioplastics include materials derived from natural biomass or produced by biological systems. Bioplastics are a better alternative to petroleum-based plastics and provide many benefits to the environment. For example, many bioplastics are derived from plant biomass, which means that the CO2 emissions caused by manufacturing can be offset by the CO2 absorbed during plant growth. Some bioplastics can also naturally biodegrade into building blocks that can be used by natural organisms, which prevents long-term waste accumulation. Thus, the adoption of sustainable bioplastics will make a positive impact on our future.
The term “circular economy” refers to the ability of a product to re-enter an economic supply chain post end-of-life. However, most plastics usage today follows a linear economy. For example, only about 14% of plastic packaging items are collected for recycling, while the rest are sent to landfills, incineration plants, or leak into the environment. From that amount, 8% is sent to cascaded recycling, where they are turned into lower-value products, and only 2% is maintained in a closed loop, where it can be continuously reused or recycled into a product of similar quality (MacArthur Foundation, 2020). Virgin feedstock must be continuously added to create new plastic materials. The cost of this is extremely massive: every year, an estimated $2.2 trillion USD is lost to plastic pollution (Frontiers, 2019), and that number continues to grow.
Development and use of bioplastics can help close the loop for the plastics economy. By replacing conventional plastics with bioplastics, the use of non-renewable petroleum-based virgin feedstock can be reduced. Furthermore, biodegradable bioplastics can be used to generate benign, high value products at their end-of-life rather than contributing to accumulating plastic waste in the environment.
There are many ways to classify bioplastics. However, there are three main groups: bio-based plastics, biodegradable plastics, and plastics that fall under both categories.
Bio-based plastics are partially or fully derived from plant/fungi biomass (e.g. corn, algae, mycelium) or from animals (e.g. silk, collagen). Some examples of commercially available bio-based plastics include bio-polyethylene tetraphthalate (bioPET), bio-polyethylene (bioPE), and bio-polytrimethylene tetraphthalate (bioPTT). While bio-based plastics do not use non-renewable petroleum-based resources, they are not necessarily biodegradable, meaning that they can still potentially accumulate as waste in the environment.
Biodegradable plastics can be broken down by biological organisms, such as bacteria or fungi. In some cases, this degradation process can be used create useful products, such as compost or commodity chemicals. Biodegradable plastics are not necessarily bio-based. For example, polybutylene adipate terephthalate (PBAT) and polycaprolactone (PCL) are biodegradable but are made from petroleum-based resources.
Plastics that are both bio-based and biodegradable are highly desirable, as they are made using renewable resources and can also naturally break down in the environment. Examples of bio-based biodegradable plastics include polyhydroxyalkanoates (PHA), starch-based plastics, and silk.
Quite a few bioplastics are designed as drop-in replacements for conventional plastics (meaning they are chemically identical to its petroleum-derived counterpart). Example drop-in replacements include bioPE and bioPET. These drop-in replacements are not naturally biodegradable but are more readily implemented in existing products and manufacturing lines.
Some bioplastics, especially naturally derived materials, such as polysaccharides and proteins, differ substantially in chemical structure from conventional petroleum-derived plastics. While many of these bioplastics have drastically different properties than petroleum-derived plastics, some naturally produced bioplastics, such as PHAs, can potentially be used to replace conventional plastics with minimal changes to the product design and manufacturing process. Regardless of whether their properties match those of conventionally used plastics, naturally derived bioplastics have the advantage of being biodegradable in the environment.
Source: European Bioplastics, nova-Institute (2023)
Approximately 50% of bioplastics produced in 2023 are biodegradable. The remaining 50% is not biodegradable but are considered bioplastics because they are made with renewable biomass. Over time, the proportion of bioplastics that are biodegradable will likely increase.
MacArthur Foundation: Rethinking The Future of Plastics
MacArthur Foundation: Plastics And The Circular Economy
Forest, et al. 2019 (published in Frontiers in Marine Science): Eliminating Plastic Pollution
Chariot Energy: How Long Does It Take for Plastic to Decompose?
European Bioplastics Organization: Home Site
Lim, 2021 (published in Nature): Microplastics are everywhere -- but are they harmful?